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Issue 14, 2018
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Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

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Abstract

Traditional cross-couplings require stoichiometric organometallic reagents. A novel nickel-catalyzed cross-coupling reaction between aldehydes and aryl halides via hydrazone intermediates has been developed, merging the Wolff–Kishner reduction and the classical cross-coupling reactions. Aromatic aldehydes, aryl iodides and aryl bromides are especially effective in this new cross-coupling chemistry.

Graphical abstract: Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

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Article information


Submitted
05 Dec 2017
Accepted
22 Jan 2018
First published
22 Jan 2018

Chem. Commun., 2018,54, 1750-1753
Article type
Communication

Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

J. Tang, L. Lv, X. Dai, C. Li, L. Li and C. Li, Chem. Commun., 2018, 54, 1750
DOI: 10.1039/C7CC09290C

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