Functionalization with terminal organophosphonate and -arsonate groups allows for crystallization and structural characterization of elusive homometallic phosphotungstates of the {PV4WVI24} archetype. 31P NMR measurements reveal moderate stability in aqueous solution for the [(PhPO)2P4W24O92]16− derivative, enabling consecutive reactions as exemplified by the formation of a CoII-{P4W24}-based coordination polymer.
X. Yi, N. V. Izarova and P. Kögerler, Chem. Commun., 2018, 54, 2216 DOI: 10.1039/C7CC09175C
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
