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Abstract | Cited by

The selective hydrogenation of α,β-unsaturated aldehydes to unsaturated alcohols can reach high selectivity and activity at room temperature using Pt nanoparticles immobilized on a non-porous Al2O3 support stabilized by aspartic acid. Aspartic acid molecules had a significant steric effect on C[double bond, length as m-dash]C hydrogenation and could modify the electronic state of metal particles.

Graphical abstract: Selective hydrogenation of unsaturated aldehydes over Pt nanoparticles promoted by the cooperation of steric and electronic effects

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