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Issue 6, 2018
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Diamondoid architectures from halogen-bonded halides

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Abstract

The reactions between a tetrahedrally-shaped tecton, tetrakis(4-(iodoethynyl)phenyl)methane, and tetraphenylphosphonium halides readily afford interpenetrated and densely packed diamondoid architectures sustained by C–I⋯X (X = chloride, bromide, iodide) interactions. In all these halogen-bonded networks, the halide anions act as four-connecting nodes, while the tetraphenylphosphonium cations provide essential templating information and structural support.

Graphical abstract: Diamondoid architectures from halogen-bonded halides

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Article information


Submitted
17 Nov 2017
Accepted
15 Dec 2017
First published
15 Dec 2017

Chem. Commun., 2018,54, 607-610
Article type
Communication

Diamondoid architectures from halogen-bonded halides

C. A. Gunawardana, M. Đaković and C. B. Aakeröy, Chem. Commun., 2018, 54, 607
DOI: 10.1039/C7CC08839F

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