An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

Jun Liang; Ya-Qiang Xie; Xu-Sheng Wang; Qiang Wang; Tao-Tao Liu; Yuan-Biao Huang; Rong Cao

doi:10.1039/C7CC08630J

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An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO₂ fixation into cyclic carbonate†

Jun Liang,

^ab Ya-Qiang Xie,^a Xu-Sheng Wang,^b Qiang Wang,^b Tao-Tao Liu,^b Yuan-Biao Huang

*^b and Rong Cao

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fujian, Fuzhou, P. R. China
E-mail: rcao@fjirsm.ac.cn, ybhuang@fjirsm.ac.cn

Abstract

A mesoporous cationic Cr-MOF, termed FJI-C10, containing imidazolium moieties, Lewis acidic Cr³⁺ sites and free halogens is constructed for the first time by a topology-guided one-pot synthesis. FJI-C10 exhibits excellent performances in CO₂ adsorption (20.2 wt% at 273 K and 1 bar) and chemical fixation of CO₂ into cyclic carbonates without the use of co-catalyst under atmospheric pressure.

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Article information

DOI: https://doi.org/10.1039/C7CC08630J
Article type: Communication
Submitted: 09 Nov 2017
Accepted: 21 Nov 2017
First published: 21 Nov 2017

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Chem. Commun., 2018,54, 342-345

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An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO₂ fixation into cyclic carbonate

J. Liang, Y. Xie, X. Wang, Q. Wang, T. Liu, Y. Huang and R. Cao, Chem. Commun., 2018, 54, 342 DOI: 10.1039/C7CC08630J

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