Rational construction of a stable Zn4O-based MOF for highly efficient CO2 capture and conversion

Hui-Fang Zhou; Bo Liu; Lei Hou; Wen-Yan Zhang; Yao-Yu Wang

doi:10.1039/C7CC08473K

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Rational construction of a stable Zn₄O-based MOF for highly efficient CO₂ capture and conversion†

Hui-Fang Zhou,‡^a Bo Liu,‡^b Lei Hou,

^a Wen-Yan Zhang^a and Yao-Yu Wang

*^a

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* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. China
E-mail: wyaoyu@nwu.edu.cn

^b College of Chemistry & Pharmacy, Northwest A&F University, Yangling 712100, P. R. China

Abstract

By employing a carboxylate ligand derived from benzene-1,4-dicarboxylate, a chemically stable Zn₄O-based self-penetrating metal–organic framework has been rationally synthesized, which exhibits high CO₂ adsorption and efficient catalytic conversion for CO₂ cycloaddition.

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Article information

DOI: https://doi.org/10.1039/C7CC08473K
Article type: Communication
Submitted: 03 Nov 2017
Accepted: 30 Nov 2017
First published: 30 Nov 2017

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Chem. Commun., 2018,54, 456-459

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Rational construction of a stable Zn₄O-based MOF for highly efficient CO₂ capture and conversion

H. Zhou, B. Liu, L. Hou, W. Zhang and Y. Wang, Chem. Commun., 2018, 54, 456 DOI: 10.1039/C7CC08473K

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Chemical Communications