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Issue 8, 2018
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A precursor method for the synthesis of new Ce(iv) MOFs with reactive tetracarboxylate linkers

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Abstract

A precursor method has been developed to synthesize Ce(IV) MOFs that could not be prepared directly from Ce(IV) salts. Starting from Ce6 clusters, two Ce-UiO-66 analogues and four tetracarboxylate-based Ce(IV) MOFs could be synthesized. The applied method facilitates framework formation by evading reactive individual Ce(IV)-ions thereby paving the way for further development of Ce-MOFs.

Graphical abstract: A precursor method for the synthesis of new Ce(iv) MOFs with reactive tetracarboxylate linkers

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Supplementary files

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Submitted
24 Oct 2017
Accepted
01 Dec 2017
First published
08 Dec 2017

Chem. Commun., 2018,54, 876-879
Article type
Communication

A precursor method for the synthesis of new Ce(IV) MOFs with reactive tetracarboxylate linkers

S. Smolders, A. Struyf, H. Reinsch, B. Bueken, T. Rhauderwiek, L. Mintrop, P. Kurz, N. Stock and D. E. De Vos, Chem. Commun., 2018, 54, 876
DOI: 10.1039/C7CC08200B

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