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A bright NUV mechanofluorescent terpyridine-based material with a piezoelectric space group was obtained. The single crystal analysis and quantum chemical calculations indicated the existence of enhanced intermolecular and intramolecular interactions and intersystem crossing, but which did not facilitate the room temperature phosphorescence.

Graphical abstract: Bright NUV mechanofluorescence from a terpyridine-based pure organic crystal

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