Issue 20, 2018

2D europium coordination polymer as a regenerable fluorescence probe for efficiently detecting fipronil

Abstract

Recently, considerable attention has been paid to European eggs that were found to contain the poisonous insecticide fipronil. Excessive consumption of fipronil can harm the human body, in particular, the liver, thyroid, nervous system and kidneys. As a consequence, there is an urgent need to develop a method to detect fipronil. In this work, a lanthanide coordination polymer [Eu(SIP)(H2O)4]n (1) (NaH2SIP = 5-sulfoisophthalic acid monosodium salt) was synthesized and characterized by single-crystal X-ray crystallography, elemental analysis, infrared spectrum and powder X-ray diffractions. The X-ray studies show that 1 is a two-dimensional layered structure, which is constructed of fused {[Eu(H2O)4]3(SIP)3} pseudo-hexagonal grids. The luminescence properties of 1 exhibit effective recognition for fipronil in methanol solution. Furthermore, a wide linear range (10−6–10−4 M), a low detection limit of 0.8 μM, high selectivity and excellent recyclability, reveal that 1 can potentially act as a luminescence-based sensor for quantitative and highly sensitive detection of fipronil. To the best of our knowledge, it is the first time that a metal–organic coordination polymer, as a fluorescent-based probe, has been used for the detection of fipronil. Moreover, fluorescent-based test papers of 1 have also been prepared, which can be regarded as a simple and practical method for detecting fipronil.

Graphical abstract: 2D europium coordination polymer as a regenerable fluorescence probe for efficiently detecting fipronil

Supplementary files

Article information

Article type
Paper
Submitted
16 Apr 2018
Accepted
26 Aug 2018
First published
27 Aug 2018

Analyst, 2018,143, 4901-4906

2D europium coordination polymer as a regenerable fluorescence probe for efficiently detecting fipronil

S. Yang, J. Lu, S. Zhang, C. Zhang and Q. Wang, Analyst, 2018, 143, 4901 DOI: 10.1039/C8AN00701B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements