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Issue 37, 2018

RAFT polymer cross-coupling with boronic acids

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Abstract

The ability to modify the thiocarbonylthio end-groups of RAFT polymers is important for applications where an inert or highly functionalised material is required. Here we report a copper promoted cross-coupling reaction between RAFT polymer end-groups and aryl boronic acids. This method gives high conversion to the modified polymers, and is compatible with a wide variety of functional molecules.

Graphical abstract: RAFT polymer cross-coupling with boronic acids

Supplementary files

Article information


Submitted
24 Apr 2018
Accepted
17 Jul 2018
First published
18 Jul 2018

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2018,9, 7370-7375
Article type
Edge Article

RAFT polymer cross-coupling with boronic acids

H. Golf, R. O'Shea, C. Braybrook, O. Hutt, D. W. Lupton and J. F. Hooper, Chem. Sci., 2018, 9, 7370 DOI: 10.1039/C8SC01862F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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