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Issue 27, 2018
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Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

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Abstract

Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar–layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P4). Our research may provide a new approach for the synthesis of various 2D materials.

Graphical abstract: Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

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Supplementary files

Article information


Submitted
28 Mar 2018
Accepted
11 Jun 2018
First published
12 Jun 2018

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2018,9, 5912-5918
Article type
Edge Article

Synthesis of a 2D phosphorus material in a MOF-based 2D nano-reactor

M. Li, C. Ma, X. Liu, J. Su, X. Cui and Y. He, Chem. Sci., 2018, 9, 5912
DOI: 10.1039/C8SC01439F

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    [Original citation] - Published by The Royal Society of Chemistry.

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