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Issue 33, 2018, Issue in Progress
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MgTiO3:Mn4+ a multi-reading temperature nanoprobe

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Abstract

MgTiO3 nanoparticles doped with Mn4+, with homogeneous size ranging about 63.1 ± 9.8 nm, were synthesized by a molten salt assisted sol gel method. These nanoparticles have been investigated as optical thermal sensors. The luminescence of tetravalent manganese ion in octahedral environment within the perovskite host presents drastic variations with temperature. Three different thermometry approaches have been proposed and characterized. Two luminescence intensity ratios are studied. Firstly between the two R-lines of Mn4+ emission at low temperature (−250 °C and −90 °C) with a maximal sensitivity of 0.9% °C−1, but also secondly between 2E → 4A2 (R-line) and the 4T24A2 transitions. This allows studying the temperature variation within a larger temperature range (−200 °C to 50 °C) with a sensitivity between 0.6% °C−1 and 1.2% °C−1 over this range. The last proposed method is the study of the lifetime variation versus temperature. The effective lifetime value corresponds to a combination of transitions from two excited energy levels of the tetravalent manganese (2E and 4T2) in thermal equilibrium toward the fundamental 4A2 state. Since the more energetic transition (4T24A2) is spin-allowed, contrary to the 2E → 4A2 one, the lifetime drastically decreases with the increase in temperature leading to an impressive high sensitivity value of 4.1% °C−1 at 4 °C and an exceptional temperature resolution of 0.025 °C. According to their optical features, MgTiO3:Mn4+ nanoparticles are indeed suitable candidates for the luminescence temperature probes at the nanoscale over several temperature ranges.

Graphical abstract: MgTiO3:Mn4+ a multi-reading temperature nanoprobe

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Publication details

The article was received on 21 Mar 2018, accepted on 10 May 2018 and first published on 18 May 2018


Article type: Paper
DOI: 10.1039/C8RA02482K
RSC Adv., 2018,8, 18341-18346
  • Open access: Creative Commons BY-NC license
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    MgTiO3:Mn4+ a multi-reading temperature nanoprobe

    E. Glais, V. Đorđević, J. Papan, B. Viana and M. D. Dramićanin, RSC Adv., 2018, 8, 18341
    DOI: 10.1039/C8RA02482K

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