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Issue 30, 2018, Issue in Progress
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ε-Caprolactone-based solid polymer electrolytes for lithium-ion batteries: synthesis, electrochemical characterization and mechanical stabilization by block copolymerization

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Abstract

In this work, three types of polymers based on ε-caprolactone have been synthesized: poly(ε-caprolactone), polystyrene-poly(ε-caprolactone), and polystyrene-poly(ε-caprolactone-r-trimethylene carbonate) (SCT), where the polystyrene block was introduced to improve the electrochemical and mechanical performance of the material. Solid polymer electrolytes (SPEs) were produced by blending the polymers with 10–40 wt% lithium bis(trifluoromethane)sulfonimide (LiTFSI). Battery devices were thereafter constructed to evaluate the cycling performance. The best performing battery half-cell utilized an SPE consisting of SCT and 17 wt% LiTFSI as both binder and electrolyte; a Li|SPE|LiFePO4 cell that cycled at 40 °C gave a discharge capacity of about 140 mA h g−1 at C/5 for 100 cycles, which was superior to the other investigated electrolytes. Dynamic mechanical analysis (DMA) showed that the storage modulus E’ was about 5 MPa for this electrolyte.

Graphical abstract: ε-Caprolactone-based solid polymer electrolytes for lithium-ion batteries: synthesis, electrochemical characterization and mechanical stabilization by block copolymerization

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Publication details

The article was received on 12 Jan 2018, accepted on 27 Apr 2018 and first published on 08 May 2018


Article type: Paper
DOI: 10.1039/C8RA00377G
RSC Adv., 2018,8, 16716-16725
  • Open access: Creative Commons BY license
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    ε-Caprolactone-based solid polymer electrolytes for lithium-ion batteries: synthesis, electrochemical characterization and mechanical stabilization by block copolymerization

    A. Bergfelt, M. J. Lacey, J. Hedman, C. Sångeland, D. Brandell and T. Bowden, RSC Adv., 2018, 8, 16716
    DOI: 10.1039/C8RA00377G

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