Issue 2, 2018

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

Abstract

In recent years, earth-abundant transition metal catalysts have been used to make great achievements on homogenous catalysis, including the field of enantioselective hydrofunctionalization of alkenes. Minimally functionalized alkenes are a class of challenging substrates for the catalytic asymmetric hydrofunctionalization reactions. This review summarizes the advances of the highly enantioselective (≥90% ee) hydrofunctionalization reactions of minimally functionalized alkenes using earth-abundant transition metals (iron, cobalt, nickel, copper, titanium and zirconium) as catalysts.

Graphical abstract: Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

Article information

Article type
Review Article
Submitted
21 Jul 2017
Accepted
26 Sep 2017
First published
27 Sep 2017

Org. Chem. Front., 2018,5, 260-272

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

J. Chen and Z. Lu, Org. Chem. Front., 2018, 5, 260 DOI: 10.1039/C7QO00613F

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