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Issue 29, 2018
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Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

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Abstract

A panel of sterically shielded tetrazoles with different N-aryl groups were synthesized and subsequently evaluated in the photoinduced tetrazole–alkene cycloaddition reaction. It was found that increase in the HOMO energy of the corresponding nitrile imines leads to a faster cycloaddition reaction along with a red shift in the fluorescence emission of the pyrazoline cycloadduct.

Graphical abstract: Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

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Supplementary files

Article information


Submitted
13 Jun 2018
Accepted
03 Jul 2018
First published
04 Jul 2018

Org. Biomol. Chem., 2018,16, 5241-5244
Article type
Communication

Sterically shielded tetrazoles for a fluorogenic photoclick reaction: tuning cycloaddition rate and product fluorescence

P. An and Q. Lin, Org. Biomol. Chem., 2018, 16, 5241
DOI: 10.1039/C8OB01404C

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