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Issue 2, 2018
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Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate

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Abstract

The activation of aryl glycosyl sulfone donors has been achieved using scandium(III) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.

Graphical abstract: Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate

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Article information


Submitted
14 Nov 2017
Accepted
12 Dec 2017
First published
12 Dec 2017

Org. Biomol. Chem., 2018,16, 325-335
Article type
Paper

Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate

A. Xolin, R. Losa, A. Kaid, C. Tresse, J. Beau, F. Boyer and S. Norsikian, Org. Biomol. Chem., 2018, 16, 325
DOI: 10.1039/C7OB02792C

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