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Issue 1, 2018
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Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

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Abstract

A new protocol for achieving the phosphination of arenes, arenols and thiols has been disclosed. This chemistry, in which diaryl(((trifluoromethyl)sulfonyl)oxy)phosphines as a kind of electrophilic phosphination reagents are in situ generated from diarylphosphine oxides, provides an efficient and mild approach for the synthesis of aromatic organophosphorus compounds.

Graphical abstract: Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

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Article information


Submitted
25 Oct 2017
Accepted
27 Nov 2017
First published
27 Nov 2017

Org. Biomol. Chem., 2018,16, 30-33
Article type
Communication

Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

T. Yuan, S. Huang, C. Cai and G. Lu, Org. Biomol. Chem., 2018, 16, 30
DOI: 10.1039/C7OB02620J

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