Jump to main content
Jump to site search

Issue 8, 2018
Previous Article Next Article

High thermoelectric performance of graphite nanofibers

Author affiliations

Abstract

Graphite nanofibers (GNFs) have been demonstrated to be a promising material for hydrogen storage and heat management in electronic devices. Here, by means of first-principles and transport simulations, we show that GNFs can also be an excellent material for thermoelectric applications thanks to the interlayer weak van der Waals interaction that induces low thermal conductance and a step-like shape in the electronic transmission with mini-gaps, which are necessary ingredients to achieve high thermoelectric performance. This study unveils that the platelet form of GNFs in which graphite layers are perpendicular to the fiber axis can exhibit outstanding thermoelectric properties with a figure of merit ZT reaching 3.55 in a 0.5 nm diameter fiber and 1.1 in a 1.1 nm diameter one. Interestingly, by introducing 14C isotope doping, ZT can even be enhanced up to more than 5, and more than 8 if we include the effect of finite phonon mean free path, which demonstrates the amazing thermoelectric potential of GNFs.

Graphical abstract: High thermoelectric performance of graphite nanofibers

Back to tab navigation

Supplementary files

Article information


Submitted
20 Oct 2017
Accepted
17 Jan 2018
First published
18 Jan 2018

Nanoscale, 2018,10, 3784-3791
Article type
Paper

High thermoelectric performance of graphite nanofibers

V. Tran, J. Saint-Martin, P. Dollfus and S. Volz, Nanoscale, 2018, 10, 3784
DOI: 10.1039/C7NR07817J

Social activity

Search articles by author

Spotlight

Advertisements