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Issue 36, 2018
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Artificial lithium fluoride surface coating on silicon negative electrodes for the inhibition of electrolyte decomposition in lithium-ion batteries: visualization of a solid electrolyte interphase using in situ AFM

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Abstract

The solid electrolyte interphase (SEI), which is a surface layer formed on the negative electrode, plays an important role in inhibiting the reductive decomposition of the electrolyte solution in a lithium-ion battery. However, it has not been understood well which components are important for the SEI to prevent the electrolyte decomposition. Lithium fluoride (LiF), as an artificial SEI, was formed on an amorphous-Si thin film by physical vapor deposition. Changes in the surface morphology of the Si electrode with potential sweeping were investigated using in situ atomic force microscopy (AFM). Although large amounts of non-uniform surface deposits that originate from electrolyte decomposition emerged on the bare Si-film electrode during the first lithiation process, few surface deposits were observed on the LiF-coated Si-film electrode even after two cycles in an ethylene carbonate-based electrolyte solution without additives. It is clear that LiF is a required SEI component that inhibits electrolyte decomposition on Si negative electrodes.

Graphical abstract: Artificial lithium fluoride surface coating on silicon negative electrodes for the inhibition of electrolyte decomposition in lithium-ion batteries: visualization of a solid electrolyte interphase using in situ AFM

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Supplementary files

Article information


Submitted
03 Jul 2018
Accepted
29 Aug 2018
First published
29 Aug 2018

Nanoscale, 2018,10, 17257-17264
Article type
Paper
Author version available

Artificial lithium fluoride surface coating on silicon negative electrodes for the inhibition of electrolyte decomposition in lithium-ion batteries: visualization of a solid electrolyte interphase using in situ AFM

M. Haruta, Y. Kijima, R. Hioki, T. Doi and M. Inaba, Nanoscale, 2018, 10, 17257
DOI: 10.1039/C8NR05354E

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