Issue 11, 2018
From the journal:

New Journal of Chemistry

Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand†

Junyi Du,ab   Jisheng Zhang,a   Jianhua Zhu,a   Chungu Xiaa  and  Wei Sun ORCID logo *a  

* Corresponding authors

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, P. R. China
E-mail: wsun@licp.cas.cn

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

A novel nonheme chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine was synthesized and spectroscopically characterized by UV-vis, CSI-TOF MS and EPR. The appropriate half-life of about 1 h at 0 °C allows us to study its reactivity in the C–H activation of various hydrocarbons in detail. In addition, its reactivity in asymmetric sulfoxidation and C–H hydroxylation was also investigated.

Graphical abstract: Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand

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Article information

DOI
https://doi.org/10.1039/C8NJ00964C
Article type
Letter
Submitted
27 Feb 2018
Accepted
09 Apr 2018
First published
10 Apr 2018

New J. Chem., 2018,42, 8315-8319

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Synthesis, characterization, and reactivity of a chiral Fe(IV)–oxo complex bearing an L-proline-derived aminopyridine ligand

J. Du, J. Zhang, J. Zhu, C. Xia and W. Sun, New J. Chem., 2018, 42, 8315 DOI: 10.1039/C8NJ00964C

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