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Issue 27, 2018
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Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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Abstract

A neutral heterobimetallic triple-decker stannole complex was prepared by the reaction of an anionic ruthenocene bearing a stannole dianionic ligand with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene), and the resulting Ru–Rh complex exhibits an electronic property different from those of the corresponding Ru–Ru and Rh–Rh complexes. The Ru–Rh complex can be decomposed in ionic liquids to metal nanoparticles.

Graphical abstract: Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

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Supplementary files

Article information


Submitted
13 Apr 2018
Accepted
07 May 2018
First published
10 May 2018

Dalton Trans., 2018,47, 8892-8896
Article type
Paper

Heterobimetallic triple-decker complexes derived from a dianionic aromatic stannole ligand

M. Saito, N. Matsunaga, J. Hamada, S. Furukawa, M. Minoura, S. Wegner, J. Barthel and C. Janiak, Dalton Trans., 2018, 47, 8892
DOI: 10.1039/C8DT01455H

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