Issue 20, 2018
From the journal:

Dalton Transactions

New Ni4Na2-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour†

Alena N. Kulakova,abc   Alexey N. Bilyachenko, ORCID logo *ab   Alexander A. Korlyukov,ad   Jérôme Long, ORCID logo c   Mikhail M. Levitsky,a   Elena S. Shubina,a   Yannick Guari ORCID logo c  and  Joulia Larionova ORCID logo c  

* Corresponding authors

a A.N.Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilov str., 28, 119991 Moscow, Russia
E-mail: bilyachenko@ineos.ac.ru

b Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklay Street 6, 117198 Moscow, Russia

c Institut Charles Gerhardt, UMR5253, University of Montpellier, ENSCM, CNRS, Pl. Eugène Bataillon, 34095 Montpellier Cedex 05, France

d Pirogov Russian National Research Medical University, Ostrovitianov str., 1, 117997 Moscow, Russia

Abstract

The first Ni(II)-based metallagermaniumsesquioxane cage compound [(PhGeO1.5)10(NiO)4(NaO0.5)2] presents a sandwich-like structure where two germsesquioxane cages are linked through an {NiO}4 core and exhibits slow dynamics of the magnetization.

Graphical abstract: New Ni4Na2-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour

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Article information

DOI
https://doi.org/10.1039/C8DT00900G
Article type
Communication
Submitted
08 Mar 2018
Accepted
13 Apr 2018
First published
16 Apr 2018

Dalton Trans., 2018,47, 6893-6897

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New Ni4Na2-phenylgermsesquioxane architecture: synthesis, structure and slow dynamic behaviour

A. N. Kulakova, A. N. Bilyachenko, A. A. Korlyukov, J. Long, M. M. Levitsky, E. S. Shubina, Y. Guari and J. Larionova, Dalton Trans., 2018, 47, 6893 DOI: 10.1039/C8DT00900G

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