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Issue 82, 2018
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Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

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Abstract

The reported Cu(II) metal–organic cage (Cu3L2, 1) can be a highly active reusable catalyst to homogeneously catalyze the A3-coupling reaction in CHCl3 and can be heterogeneously recovered by simply adding 1,4-dioxane via formation of the insoluble metal–organic framework (Cu3L2(1,4-dioxane)1.5, 2).

Graphical abstract: Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

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Supplementary files

Article information


Submitted
05 Sep 2018
Accepted
19 Sep 2018
First published
20 Sep 2018

Chem. Commun., 2018,54, 11550-11553
Article type
Communication

Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

G. Chen, C. Chen, X. Li, H. Ma and Y. Dong, Chem. Commun., 2018, 54, 11550
DOI: 10.1039/C8CC07208F

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