Yuki Shimizu, Yoshiaki Shoji, Daisuke Hashizume, Yuuya Nagata and Takanori Fukushima
Chem. Commun., 2018,54, 12314-12317
DOI:
10.1039/C8CC06277C,
Communication
Although the chiral enrichment of dynamic prochiral molecules usually requires a strong interaction with a chiral source, the enantiomer ratio of a propeller-shaped molecule, obtained by a recently developed boron-mediated benzannulation reaction of alkynes, is biased in various organic solvents through solvation for the propeller moieties.
