Issue 78, 2018
From the journal:

Chemical Communications

Arsagermene, a compound with an –As[double bond, length as m-dash]Ge[double bond splayed right] double bond†

Vladimir Ya. Lee, ORCID logo *a   Manami Kawai,a   Olga A. Gapurenko,b   Vladimir I. Minkin, ORCID logo b   Heinz Gornitzkac  and  Akira Sekiguchi ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Ibaraki, Japan
E-mail: leevya@chem.tsukuba.ac.jp

b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov on Don 344090, Russian Federation

c CNRS, LCC, Université de Toulouse, UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France

Abstract

The first compound featuring an As[double bond, length as m-dash]Ge double bond, arsagermene Mes*As[double bond, length as m-dash]Ge(SiMetBu2)2, was synthesized, isolated and fully characterized. Crystallographic studies revealed that arsagermene has a planar Ge[double bond, length as m-dash]As bond of 2.2731(8) Å, which is notably shorter than the standard Ge–As single bond. The double bond character of arsagermene was further supported by computational data.

Graphical abstract: Arsagermene, a compound with an –As [[double bond, length as m-dash]] Ge [[double bond splayed right]] double bond

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Article information

DOI
https://doi.org/10.1039/C8CC05630G
Article type
Communication
Submitted
12 Jul 2018
Accepted
01 Aug 2018
First published
01 Aug 2018

Chem. Commun., 2018,54, 10947-10949

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Arsagermene, a compound with an –As[double bond, length as m-dash]Ge[double bond splayed right] double bond

V. Ya. Lee, M. Kawai, O. A. Gapurenko, V. I. Minkin, H. Gornitzka and A. Sekiguchi, Chem. Commun., 2018, 54, 10947 DOI: 10.1039/C8CC05630G

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