Issue 72, 2018

{Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

Abstract

Two poly-oxo cluster complexes of tetravalent neptunium (Np(IV)), Np38O56Cl18(bz)24(THF)8·nTHF and Np38O56Cl42(ipa)20·mipa (bz = benzoate, THF = tetrahydrofuran, and ipa = isopropanol), were obtained via solvothermal synthesis and structurally characterised by single-crystal X-ray diffraction. The {Np38} clusters are comparable to the analogous {U38} and {Pu38} motifs, filling the gap in this largest poly-oxo cluster series of tetravalent actinides.

Graphical abstract: {Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

Supplementary files

Article information

Article type
Communication
Submitted
09 May 2018
Accepted
12 Jul 2018
First published
22 Aug 2018
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2018,54, 10060-10063

{Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

N. P. Martin, C. Volkringer, P. Roussel, J. März, C. Hennig, T. Loiseau and A. Ikeda-Ohno, Chem. Commun., 2018, 54, 10060 DOI: 10.1039/C8CC03744B

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