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Issue 16, 2018
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Goodbye to S2− in aqueous solution

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Abstract

New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2−(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2−(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.

Graphical abstract: Goodbye to S2− in aqueous solution

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Article information


Submitted
09 Jan 2018
Accepted
30 Jan 2018
First published
30 Jan 2018

Chem. Commun., 2018,54, 1980-1983
Article type
Communication

Goodbye to S2− in aqueous solution

P. M. May, D. Batka, G. Hefter, E. Königsberger and D. Rowland, Chem. Commun., 2018, 54, 1980
DOI: 10.1039/C8CC00187A

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