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Issue 10, 2018
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A metal–metalloporphyrin framework based on an octatopic porphyrin ligand for chemical fixation of CO2 with aziridines

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Abstract

A new porous metal–metalloporphyrin framework, MMPF-10, has been constructed from an octatopic porphyrin ligand, which links copper paddlewheel units to form a framework with fmj topology. In situ metallation of the porphyrin ligands provides MMPF-10 with two unique accessible Cu(II) centers. This allows it to behave as an efficient Lewis acid catalyst in the first reported reaction of CO2 with aziridines to synthesize oxazolidinones catalyzed by an MMPF.

Graphical abstract: A metal–metalloporphyrin framework based on an octatopic porphyrin ligand for chemical fixation of CO2 with aziridines

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Supplementary files

Article information


Submitted
17 Nov 2017
Accepted
08 Dec 2017
First published
08 Dec 2017

Chem. Commun., 2018,54, 1170-1173
Article type
Communication

A metal–metalloporphyrin framework based on an octatopic porphyrin ligand for chemical fixation of CO2 with aziridines

X. Wang, W. Gao, Z. Niu, L. Wojtas, J. A. Perman, Y. Chen, Z. Li, B. Aguila and S. Ma, Chem. Commun., 2018, 54, 1170
DOI: 10.1039/C7CC08844B

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