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Issue 96, 2018
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Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

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Abstract

We encapsulated anionic [Mo3S13]2− clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g−1 h−1 under visible-light irradiation over the course of 18 hours.

Graphical abstract: Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

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Supplementary files

Article information


Submitted
28 Sep 2018
Accepted
06 Nov 2018
First published
06 Nov 2018

Chem. Commun., 2018,54, 13563-13566
Article type
Communication

Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

Y. Cheng, R. Wang, S. Wang, X. Xi, L. Ma and S. Zang, Chem. Commun., 2018, 54, 13563
DOI: 10.1039/C8CC07784C

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