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Issue 71, 2018
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Facile synthesis and efficient electrochemiluminescence of a readily accessible pyridopyrimidine

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Abstract

Through a facile one-pot three-component reaction and a subsequent acetylation strategy, a novel greenish-blue fluorescent 4-imino-4H-pyrido[1,2-a]pyrimidine-3-carbonitrile (IPPC) was synthesized. Electrochemiluminescence (ECL) of IPPC was firstly found to produce efficient emission at 500 nm with reducing coreactants. Its very similar ECL and PL spectra suggest that ECL production is mainly from the monomeric excited states.

Graphical abstract: Facile synthesis and efficient electrochemiluminescence of a readily accessible pyridopyrimidine

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Publication details

The article was received on 08 Jul 2018, accepted on 31 Jul 2018 and first published on 01 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05490H
Chem. Commun., 2018,54, 9897-9900

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    Facile synthesis and efficient electrochemiluminescence of a readily accessible pyridopyrimidine

    R. Zhang, F. Tong, L. Yang, J. R. Adsetts, T. Yan, R. Wang, Z. Ding and H. Wang, Chem. Commun., 2018, 54, 9897
    DOI: 10.1039/C8CC05490H

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