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Issue 68, 2018
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Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

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Abstract

Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.

Graphical abstract: Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

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Article information


Submitted
30 May 2018
Accepted
25 Jul 2018
First published
26 Jul 2018

Chem. Commun., 2018,54, 9450-9453
Article type
Communication

Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

J. C. Gee, B. A. Fuller, H. Lockett, G. Sedghi, C. M. Robertson and K. V. Luzyanin, Chem. Commun., 2018, 54, 9450
DOI: 10.1039/C8CC04287J

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