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Issue 56, 2018
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Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration

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Abstract

The molecular water oxidation catalyst [Ru(bda)(L)2] has been incorporated into pyridine-decorated MIL-101(Cr) metal–organic frameworks. The resulting MIL-101@Ru materials exhibit turnover frequencies (TOFs) up to ten times higher compared to the homogenous reference. An unusual dependence of the formal TOFs on oxidant concentration is observed that ultimately arises from differing amounts of catalysts in the MOF crystals being active.

Graphical abstract: Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration

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Supplementary files

Article information


Submitted
24 Mar 2018
Accepted
12 Jun 2018
First published
12 Jun 2018

This article is Open Access

Chem. Commun., 2018,54, 7770-7773
Article type
Communication

Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration

A. Bhunia, B. A. Johnson, J. Czapla-Masztafiak, J. Sá and S. Ott, Chem. Commun., 2018, 54, 7770
DOI: 10.1039/C8CC02300J

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