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Issue 24, 2018
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Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom

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Abstract

We present here the first example of C(sp3)–H activation directed by a sulfur atom. Based on this transformation catalyzed by Ru/C, we have developed a hydrogen isotope exchange reaction for the deuterium and tritium labelling of thioether substructures in complex molecules.

Graphical abstract: Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom

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Article information


Submitted
25 Jan 2018
Accepted
22 Feb 2018
First published
05 Mar 2018

Chem. Commun., 2018,54, 2986-2989
Article type
Communication

Ruthenium-catalyzed hydrogen isotope exchange of C(sp3)–H bonds directed by a sulfur atom

L. Gao, S. Perato, S. Garcia-Argote, C. Taglang, L. M. Martínez-Prieto, C. Chollet, D. Buisson, V. Dauvois, P. Lesot, B. Chaudret, B. Rousseau, S. Feuillastre and G. Pieters, Chem. Commun., 2018, 54, 2986
DOI: 10.1039/C8CC00653A

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