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Abstract | Cited by

An unprecedented copper(I)-catalyzed asymmetric inverse electron demand Diels–Alder reaction of azoalkenes with fulvenes is reported. This methodology offers a directed entry to synthesize bicyclic tetrapyridazine derivatives in good yield with exclusive regioselectivity and excellent stereoselectivity.

Graphical abstract: Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

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