Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

Liang Wei; Qiao Zhu; Zhi-Min Song; Kang Liu; Chun-Jiang Wang

doi:10.1039/C7CC09896K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes†

Liang Wei,‡^a Qiao Zhu,‡^a Zhi-Min Song,^a Kang Liu^a and Chun-Jiang Wang

*^ab

Author affiliations

* Corresponding authors

^a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
E-mail: cjwang@whu.edu.cn
Fax: +86-27-68754067

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, China

Abstract

An unprecedented copper(I)-catalyzed asymmetric inverse electron demand Diels–Alder reaction of azoalkenes with fulvenes is reported. This methodology offers a directed entry to synthesize bicyclic tetrapyridazine derivatives in good yield with exclusive regioselectivity and excellent stereoselectivity.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7CC09896K
Article type: Communication
Submitted: 27 Dec 2017
Accepted: 11 Feb 2018
First published: 12 Feb 2018

Download Citation

Chem. Commun., 2018,54, 2506-2509

Permissions

Request permissions

Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

L. Wei, Q. Zhu, Z. Song, K. Liu and C. Wang, Chem. Commun., 2018, 54, 2506 DOI: 10.1039/C7CC09896K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Catalytic asymmetric inverse electron demand Diels–Alder reaction of fulvenes with azoalkenes

Social activity

Search articles by author

Spotlight

Advertisements