Issue 8, 2018

A precursor method for the synthesis of new Ce(iv) MOFs with reactive tetracarboxylate linkers

Abstract

A precursor method has been developed to synthesize Ce(IV) MOFs that could not be prepared directly from Ce(IV) salts. Starting from Ce6 clusters, two Ce-UiO-66 analogues and four tetracarboxylate-based Ce(IV) MOFs could be synthesized. The applied method facilitates framework formation by evading reactive individual Ce(IV)-ions thereby paving the way for further development of Ce-MOFs.

Graphical abstract: A precursor method for the synthesis of new Ce(iv) MOFs with reactive tetracarboxylate linkers

Supplementary files

Article information

Article type
Communication
Submitted
24 Oct 2017
Accepted
01 Dec 2017
First published
08 Dec 2017

Chem. Commun., 2018,54, 876-879

A precursor method for the synthesis of new Ce(IV) MOFs with reactive tetracarboxylate linkers

S. Smolders, A. Struyf, H. Reinsch, B. Bueken, T. Rhauderwiek, L. Mintrop, P. Kurz, N. Stock and D. E. De Vos, Chem. Commun., 2018, 54, 876 DOI: 10.1039/C7CC08200B

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