Issue 14, 2018
From the journal:

Chemical Communications

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks†

Kang Zhang,a   Yunjun Shen,a   Jiyong Liu,a   Bernhard Spinglerb  and  Simon Duttwyler ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Zhejiang University, Zheda Road 38, Hangzhou, P. R. China
E-mail: duttwyler@zju.edu.cn

b Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland

Abstract

The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CB11H11]āˆ’ is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster Cā€“[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

Graphical abstract: Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC07724F
Article type
Communication
Submitted
05 Oct 2017
Accepted
22 Dec 2017
First published
22 Dec 2017

Chem. Commun., 2018,54, 1698-1701

Permissions

Request permissions

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

K. Zhang, Y. Shen, J. Liu, B. Spingler and S. Duttwyler, Chem. Commun., 2018, 54, 1698 DOI: 10.1039/C7CC07724F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements