Issue 14, 2018

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Abstract

The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CB11H11] is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

Graphical abstract: Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Supplementary files

Article information

Article type
Communication
Submitted
05 Oct 2017
Accepted
22 Dec 2017
First published
22 Dec 2017

Chem. Commun., 2018,54, 1698-1701

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

K. Zhang, Y. Shen, J. Liu, B. Spingler and S. Duttwyler, Chem. Commun., 2018, 54, 1698 DOI: 10.1039/C7CC07724F

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