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Issue 15, 2018
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Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

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Abstract

A copper-mediated oxidative isoperfluoropropylation of unactivated terminal alkenes with commercially available hexafluoropropylene (HFP) has been developed. With operational simplicity of the procedure and broad substrate applicability, this strategy provides a general and straightforward way for the construction of C(sp3)–C3F7-i bonds. A variety of allylic isoperfluoropropylated compounds have been efficiently synthesized using this strategy.

Graphical abstract: Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

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Publication details

The article was received on 09 Oct 2017, accepted on 19 Jan 2018 and first published on 19 Jan 2018


Article type: Communication
DOI: 10.1039/C7CC07614B
Chem. Commun., 2018,54, 1877-1880

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    Direct oxidative isoperfluoropropylation of terminal alkenes via hexafluoropropylene (HFP) and silver fluoride

    X. Wang and Y. Wu, Chem. Commun., 2018, 54, 1877
    DOI: 10.1039/C7CC07614B

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