The role of Ln3+ (Ln = Eu, Yb) in persistent red luminescence in MgGeO3:Mn2+

Abstract

In this paper, Mn²⁺ and Ln³⁺ (Ln = Eu, Yb) co-doped MgGeO₃ phosphors were prepared using a solid state reaction technique, and their optical properties were investigated. Mn²⁺-doped samples exhibit persistent luminescence in the red region, peaking at 677 nm, because of the ⁴T₁ → ⁶A₁ transition of the Mn²⁺ ions under ultraviolet (UV) excitation. Based on the charge transfer (CT) transition of Eu³⁺ and the band-gap energy, energy level diagrams with divalent lanthanide ground states relative to the conduction and valence band edges were constructed. ΔE(Ln), (Ln = Eu, Yb), which represents the energy gaps between the divalent lanthanide ground states and the bottom of the conduction band, were found to be 0.95 and 0.52 eV, respectively. Compared to a Mn²⁺ singly-doped sample, the thermoluminescence (TL) glow curves of the Mn²⁺–Eu³⁺ co-doped sample and the Mn²⁺–Yb³⁺ co-doped sample showed an additional TL glow peak at approximately 502 and 332 K with trap depths (E_trap) of 1.49 and 0.99 eV, respectively. The correspondence of E_trap with ΔE(Ln) suggests that Eu³⁺ and Yb³⁺ themselves work as electron traps in the MgGeO₃:Mn²⁺ phosphors. We have also demonstrated that the Mn²⁺–Eu³⁺ co-doped material could be a good probe with photo-stimulated functions for long-term in vivo imaging owing to its deeper trap depth.