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Issue 27, 2017
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Linking design and properties of purine-based donor–acceptor chromophores as optoelectronic materials

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Abstract

Creating new building blocks for donor–acceptor conjugated systems is an important task for continued development of materials for organic electronics. Purines were introduced into small-molecule π-conjugated systems via Stille cross-coupling using stannylated derivatives of benzodithiophene, thiophene, or dithienylbenzothiadiazole to generate a series of “purine–π–purine” chromophores having high thermal stability, long excited-state lifetimes, and high quantum yields. Photophysical and electrochemical property characterization indicate that depending on the choice of a conjugated bridging unit, purines behave as either an electron-donating or an electron-accepting unit in these small-molecule donor–acceptor chromophores. Specifically, while purine chromophores do not exhibit charge transfer character when linked to a thiophene unit, purinyl units act as a weak acceptor when coupled with benzodithiophene and as a weak donor when coupled with dithienylbenzothiadiazole. In addition to fundamental insights into the molecular design of purine-based chromophores and their charge-transfer character, the results and synthetic tailorability of purines suggest that they may be compelling building blocks in conjugated materials for optical and electronic devices and sensors.

Graphical abstract: Linking design and properties of purine-based donor–acceptor chromophores as optoelectronic materials

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Supplementary files

Article information


Submitted
27 Apr 2017
Accepted
17 Jun 2017
First published
03 Jul 2017

J. Mater. Chem. C, 2017,5, 6891-6898
Article type
Paper

Linking design and properties of purine-based donor–acceptor chromophores as optoelectronic materials

G. S. Collier, L. A. Brown, E. S. Boone, M. Kaushal, M. N. Ericson, M. G. Walter, B. K. Long and S. M. Kilbey, J. Mater. Chem. C, 2017, 5, 6891
DOI: 10.1039/C7TC01835E

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