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Issue 24, 2017
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Flexible and highly efficient perovskite solar cells with a large active area incorporating cobalt-doped poly(3-hexylthiophene) for enhanced open-circuit voltage

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Abstract

Poly(3-hexylthiophene) (P3HT) is a promising p-type polymer to optimize the architecture, charge transfer, and environmental stability in electronic devices. Therefore, it can be a suitable material for a hole transporting layer in lead halide perovskite solar cells (PSCs). However, the mismatch of band alignment with perovskites suppresses efficient charge extraction and transfer. This results in the significant loss of open-circuit voltage (Voc) and resultant device performance deterioration. Therefore, modifying the energy level is essential to improve band alignment with perovskites. Here, a cobalt complex, tris(2-(1H-pyrazol-1-yl)pyridine) cobalt(II) di[bis(trifluoromethane)sulfonimide] (Co(II)-TFSI) is used as a p-dopant in P3HT. This enhances the conductivity and leads to a downward shift of the energy levels. The efficient charge extraction and transfer from perovskite considerably improves the device performance, resulting in a power conversion efficiency (PCE) of 16.28% and Voc of 1.061 V. Moreover, a flexible device incorporating Co-P3HT exhibits impressive 11.84% PCE and mechanical stability up to 600 bending cycles. And the flexible Co-P3HT device shows better air stability than the Li-doped P3HT (Li-P3HT) device for 40 days. These results suggest that Co(II)-TFSI is an alternative to Li salts to realize high performance in PSCs incorporating polythiophene derivatives.

Graphical abstract: Flexible and highly efficient perovskite solar cells with a large active area incorporating cobalt-doped poly(3-hexylthiophene) for enhanced open-circuit voltage

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Supplementary files

Article information


Submitted
25 Apr 2017
Accepted
29 May 2017
First published
05 Jun 2017

J. Mater. Chem. A, 2017,5, 12158-12167
Article type
Paper

Flexible and highly efficient perovskite solar cells with a large active area incorporating cobalt-doped poly(3-hexylthiophene) for enhanced open-circuit voltage

J. W. Jung, J. Park, I. K. Han, Y. Lee, C. Park, W. Kwon and M. Park, J. Mater. Chem. A, 2017, 5, 12158
DOI: 10.1039/C7TA03541A

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