A novel thermo-responsive supramolecular organogel based on dual acylhydrazone: fluorescent detection for Al3+ ions

Xinxian Ma; Shiwei Liu; Zhifeng Zhang; Yanbing Niu; Jincai Wu

doi:10.1039/C7SM02141K

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A novel thermo-responsive supramolecular organogel based on dual acylhydrazone: fluorescent detection for Al³⁺ ions†

Xinxian Ma,

*^a Shiwei Liu,^a Zhifeng Zhang,^a Yanbing Niu^a and Jincai Wu

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Ningxia Normal University, People's Republic of China
E-mail: maxinxian@163.com
Fax: +86 954 2079637
Tel: +86 954 2079637

^b Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, People's Republic of China
E-mail: wujc@lzu.edu.cn
Fax: +86 931 8912580
Tel: +86 931 8912582

Abstract

A new dual acylhydrazone-functionalized gelator (L) has been synthesized, which behaves as a thermal-responsive supramolecular organogel (L-gel) in DMSO. This L-gel exhibits very weak fluorescence based on the photoinduced electron transfer (PET) mechanism. The L-gel can recognize Al³⁺ and assemble into an enhanced blue-light-emitting supramolecular metallogel (Al@gel).

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Supplementary information PDF (801K)

Article information

DOI: https://doi.org/10.1039/C7SM02141K
Article type: Communication
Submitted: 31 Oct 2017
Accepted: 15 Nov 2017
First published: 15 Nov 2017

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Soft Matter, 2017,13, 8882-8885

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A novel thermo-responsive supramolecular organogel based on dual acylhydrazone: fluorescent detection for Al³⁺ ions

X. Ma, S. Liu, Z. Zhang, Y. Niu and J. Wu, Soft Matter, 2017, 13, 8882 DOI: 10.1039/C7SM02141K

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