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Issue 5, 2017
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Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

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Abstract

Manganese-catalyzed sequential C–H and C–C/C–Het bond activation to synthesize allylic alcohols, allylated arenes, functionalized cyclopentenes and skipped dienes is reported. This protocol can be readily scaled up and various coupling partners are applied in manganese catalysis for the first time. Moreover, manganese-catalyzed alkenyl C(sp2)–H activation is also shown. Complimentary to the standard solution-based protocols, these reactions also proceed efficiently under neat conditions, which is unprecedented for abundant metal catalyzed C–H activation reactions.

Graphical abstract: Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

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Supplementary files

Article information


Submitted
16 Jan 2017
Accepted
24 Feb 2017
First published
24 Feb 2017

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2017,8, 3379-3383
Article type
Edge Article

Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

Q. Lu, F. J. R. Klauck and F. Glorius, Chem. Sci., 2017, 8, 3379
DOI: 10.1039/C7SC00230K

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