Issue 4, 2018
From the journal:

Chemical Communications

Crystalline and permanently porous porphyrin-based metal tetraphosphonates†

Timo Rhauderwiek,a   Konrad Wolkersdörfer,b   Sigurd Øien-Ødegaard,c   Karl-Petter Lillerud,c   Michael Wark ORCID logo b  and  Norbert Stock ORCID logo *ac  

* Corresponding authors

a Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth Straße 2, D-24118 Kiel, Germany
E-mail: stock@ac.uni-kiel.de

b Chemical Technology 1, Carl von Ossietzky University Oldenburg, Carl-von-Ossietzky Str. 9-11, D-26129 Oldenburg, Germany

c Department of Chemistry, University of Oslo, Sem Sælands vei 26, N-0371 Oslo, Norway

Abstract

The new porphyrin-based tetraphosphonic acid (Ni-H8TPPP) was employed in the synthesis of four isostructural MOFs of composition [M(Ni-H6TPPP)(H2O)], denoted CAU-29 (M = Mn, Co, Ni, Cd). Ni-CAU-29 was thoroughly characterized regarding its thermal and chemical stability as well as for proton conductivity.

Graphical abstract: Crystalline and permanently porous porphyrin-based metal tetraphosphonates

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Article information

DOI
https://doi.org/10.1039/C7CC07766A
Article type
Communication
Submitted
07 Oct 2017
Accepted
08 Dec 2017
First published
08 Dec 2017

Chem. Commun., 2018,54, 389-392

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Crystalline and permanently porous porphyrin-based metal tetraphosphonates

T. Rhauderwiek, K. Wolkersdörfer, S. Øien-Ødegaard, K. Lillerud, M. Wark and N. Stock, Chem. Commun., 2018, 54, 389 DOI: 10.1039/C7CC07766A

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