Cu2(BDC)2(BPY)–MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan–Lam coupling prepared via ball-milling strategy

Abstract

Nanoporous Cu₂(BDC)₂(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu₂(BDC)₂(BPY) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) surface area analysis.