Enhanced persistent properties of Mn2+ activated CaZnOS

Abstract

The red emitting CaZnOS:Mn²⁺ long persistent phosphor was successfully prepared via a conventional high-temperature solid-state reaction method. The persistent luminescence emission of Mn²⁺-doped CaZnOS phosphor was investigated for the first time. Rare-earth trivalent ions were used as co-dopants to obtain a brighter red afterglow and longer persistence time. The optical properties of the as-prepared samples have been investigated systematically by employing photoluminescence spectroscopy, persistent luminescence spectroscopy, afterglow decay curves and thermoluminescence curves. In light of the experimental results of this study, a possible mechanism of persistent luminescence was illustrated and discussed in detail. These investigations provide a new and efficient long persistent phosphor.