Issue 18, 2017, Issue in Progress
From the journal:

RSC Advances

Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

A. Hernandez-Cid, ORCID logo a   M. Piekarska,a   R. W. Adams, ORCID logo a   M. Nilsson, ORCID logo a   R. Evans ORCID logo b  and  G. A. Morris ORCID logo *a  

* Corresponding authors

a School of Chemistry, University of Manchester, Manchester M13 9PL, UK
E-mail: g.a.morris@manchester.ac.uk

b Aston Institute of Materials Research, School of Engineering and Applied Science, Aston University, Birmingham, UK

Abstract

Mixtures of species of similar sizes can be analysed with 1H NMR using diffusion-ordered spectroscopy (DOSY), by adding a co-solute with which different analytes interact to different extents (“matrix-assisted DOSY”). A matrix containing aqueous perfluorooctanoate micelles has the dual advantages of invisibility to 1H NMR, and interactions tuneable by adjusting the pH.

Graphical abstract: Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

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Article information

DOI
https://doi.org/10.1039/C7RA00188F
Article type
Paper
Submitted
05 Jan 2017
Accepted
02 Feb 2017
First published
08 Feb 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 10757-10762

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Matrix-assisted diffusion-ordered NMR spectroscopy with an invisible, tuneable matrix

A. Hernandez-Cid, M. Piekarska, R. W. Adams, M. Nilsson, R. Evans and G. A. Morris, RSC Adv., 2017, 7, 10757 DOI: 10.1039/C7RA00188F

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