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Abstract | Cited by

We pioneer a self-reporting profluorescent release system driven by the thermo-reversible dynamic covalent ligation of chromophores to a lateral polymer chain, whose fluorescence is silenced by unpaired spins of nitroxide moieties prior to release. The introduced technology platform holds significant potential for imaging substrate release events.

Graphical abstract: Spin fluorescence silencing enables an efficient thermally driven self-reporting polymer release system

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