A pyrene based fluorescent turn-on chemosensor: aggregation-induced emission enhancement and application towards Fe3+ and Fe2+ recognition

Abstract

A pyrene-based probe bearing benzothiazole ionophore (Py-BTZ) was synthesised as a “turn-on” fluorescent chemosensor for the detection of Fe³⁺ and Fe²⁺ ions in CH₃CN : H₂O (1 : 1, v/v) solvent mixes. The chemosensor showed optical as well as colorimetric changes towards Fe³⁺ and Fe²⁺ ions along with a remarkable enhancement in fluorescence emission. The detection limit of Py-BTZ towards Fe³⁺ and Fe²⁺ ions was found to be 2.61 μM and 2.06 μM, respectively. The binding of Py-BTZ with Fe³⁺ and Fe²⁺ was determined by using FT-IR experiments. Interestingly, Py-BTZ shows aggregation induced emission enhancement (AIEE) properties in polar solvent mixes such as CH₃CN : H₂O (1 : 1, v/v).