Issue 2, 2017
From the journal:

Photochemical & Photobiological Sciences

Pulsed Nd:YAG laser-induced photoreaction of cis,cis-1,3-cyclooctadiene at 266 nm: selective cyclization to cis-bicyclo[4.2.0]oct-7-ene†

Keiko Komori-Orisaku, ORCID logo a   Yui Hiroseb  and  Izumi Iwakura*ac  

* Corresponding authors

a Department Research Institute of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Yokohama 221-8686, Japan

b Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Yokohama, Japan

c Department of Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Yokohama 221-8686, Japan
E-mail: izumi@kanagawa-u.ac.jp

Abstract

Nanosecond-scale pulsed laser irradiation of cis,cis-1,3-cyclooctadiene via an Nd:YAG laser at 266 nm induced highly selective cyclization of the 1,3-diene moiety to afford cis-bicyclo[4.2.0]oct-7-ene in high yield. The pulsed Nd:YAG laser light is highly monochromatic thereby allowing efficient control of the photoreaction selectivity by controlling the photostationary state.

Graphical abstract: Pulsed Nd:YAG laser-induced photoreaction of cis,cis-1,3-cyclooctadiene at 266 nm: selective cyclization to cis-bicyclo[4.2.0]oct-7-ene

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Article information

DOI
https://doi.org/10.1039/C6PP00323K
Article type
Communication
Submitted
02 Sep 2016
Accepted
06 Dec 2016
First published
07 Dec 2016

Photochem. Photobiol. Sci., 2017,16, 146-150

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Pulsed Nd:YAG laser-induced photoreaction of cis,cis-1,3-cyclooctadiene at 266 nm: selective cyclization to cis-bicyclo[4.2.0]oct-7-ene

K. Komori-Orisaku, Y. Hirose and I. Iwakura, Photochem. Photobiol. Sci., 2017, 16, 146 DOI: 10.1039/C6PP00323K

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