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Issue 44, 2017
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Photochemical and oxidative cyclisation of tetraphenylpyrroles

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Abstract

The photochemical and oxidative cyclodehydrogenation reactions of tetraphenylpyrroles act in a complementary fashion for the cyclisation of N-ethyl and N-benzyl derivatives. In the case of the former, a doubly cyclised product was isolated from cyclisation with solid FeCl3, while the latter gives a rearranged 3H-pyrrole upon irradiation.

Graphical abstract: Photochemical and oxidative cyclisation of tetraphenylpyrroles

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Supplementary files

Article information


Submitted
13 Oct 2017
Accepted
25 Oct 2017
First published
25 Oct 2017

Org. Biomol. Chem., 2017,15, 9293-9296
Article type
Communication

Photochemical and oxidative cyclisation of tetraphenylpyrroles

J. L. Ferguson, M. A. Squire and C. M. Fitchett, Org. Biomol. Chem., 2017, 15, 9293
DOI: 10.1039/C7OB02537H

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